Impact of the anode operating conditions on the liquid water distribution in the cathode gas diffusion layer

Previous experimental results indicate that the humidification conditions at the anode have an impact on the liquid water distribution in the cathode gas diffusion layer. Numerical simulations are developed to reproduce and analyze this effect. Results consistent with the experimental results are first obtained by playing with the partition coefficients of an advanced pore network model computing the liquid water formation and transfer in the cathode gas diffusion layer (GDL) for a large range of operating conditions. Then, a model for the full anode – cathode assembly is developed by combining the pore network model of the cathode GDL and a 1D model describing the heat and water transfer in the various components of the anode-cathode assembly. This enables one to generalize the dry – wet regime diagram introduced in a previous work by incorporating the effect of the humidity condition at the anode.     

Do metal grain silos benefit women in Kenya,Malawi, Zambia and Zimbabwe?

Metal silos can reduce maize losses during storage in smallholder farm systems, contributing towards international goals of reducing food waste and moving towards Sustainable Development Goal 2, Zero Hunger. However, technologies are introduced into farming systems with complex sets of relationships. These may differentially affect the ability of women and men to secure the expected benefits of metal silos. This, in turn, may affect adoption rates and expected outcomes. To better understand these relationships, a mixed methods study was conducted in Kenya, Malawi, Zimbabwe and Zambia where metal silos were introduced through the Effective Grain Storage Project (EGSP). EGSP distributed 1717 metal silos across the four countries.Quantitative surveys using random sampling were conducted in Kenya (124 respondents) and Malawi (100 respondents) with metal silo owners. Qualitative surveys, using purposive sampling, were conducted in all four countries covering 14 ethnic groups using focus group discussions (360 respondents), key informant interviews (62 respondents), and household case studies (62 respondents). The aim was to understand gendered post-harvest management and storage strategies in traditional systems and to map changes when metal silos were introduced.The findings suggest roles and responsibilities regarding the ownership and management of storage structures are strongly gendered with some differences between ethnic groups and countries. Men benefit more than women from the introduction of metal silos. Ownership of the grain storage facility, and the benefits attached to ownership, can switch from women to men with women having less scope for bargaining over their rights to use the stored grain for their own needs and the benefit of all household members. Women and men fail to fully follow guidelines for effective use of metal silos. They differ in their preferred attributes for their ideal storage system. Whilst some attributes are shared, women’s preferences were sharply differentiated from men in others.     

A survey of dairy goat kid-rearing practices on Canadian farms and their associations with self-reported farm performance

Although future production of dairy goats is influenced by kid-rearing practices, little is known regarding which practices maximize kid growth, welfare, and future production success. The objectives of this survey study were to (1) identify common rearing practices of Canadian commercial dairy goat farms and evaluate their associations with 6 farm performance indicators and (2) determine if farms could be grouped by management style on the basis of the 6 performance indicators and compare rearing practices common across the different groups. A survey was sent by post or electronic media to reach dairy goat producers across Canada. The questionnaire contained 70 questions on the following areas of kid rearing: kidding management, care of newborn, colostrum management, milk and solid feeding in the preweaning period, health management, disbudding, housing conditions, weaning strategies, record keeping and growth monitoring, and farm performance data. Performance indicators, calculated on self-reported data, were 305-d milk production, preweaning mortality rate, diarrhea and respiratory disease prevalence, average daily gain from birth to weaning, herd milk production, and replacement rate. A total of 175 questionnaires were returned. After applying inclusion criteria, including herd size (≥40 goats) and completeness of surveys, 104 respondents from Ontario (n = 72, 69%), Québec (n = 23, 22%), and the Western provinces (n = 9, 9%) were retained for analysis, representing 29% of all Canadian producers. Farm sizes ranged from 42 to 2,500 (median = 190) goats. A large amount of variation in rearing practices and farm performance was found between farms. Colostrum and milk feeding management were found to be associated with all performance indicators except for kid respiratory disease prevalence, with timing of colostrum delivery and feeding method accounting for most the associations within each of the 2 areas. Replacement rate was mostly affected by whether or not kids were reared with their dam. Herds surveyed in the study could successfully be divided into 3 distinct groups (production-focused, longevity-focused, and low performance), representing different management styles on the basis of farm self-reported performance levels. Rearing practices found to be associated with higher farm performance could be targeted by advisory services to help improve management practices on Canadian dairy goat farms.     

A fuel cell powered autonomous surface vehicle: The Eco-SWAMP project

Autonomous surface vehicles are becoming consolidated robotic tools for marine, coastal and inland surveys. Autonomous surface vehicles are usually equipped with electronic instruments to perform remotely controlled or autonomous geo-morphological, biological, chemical, physical analyses and data collection. Actually, well-established solutions provide battery power but the research focuses on introducing a fuel cell to decrease the environmental impact meanwhile increasing the cruising range. In this paper, the design of the Eco-SWAMP, a fuel cell powered autonomous surface vehicle, is presented starting from its battery-powered version, the SWAMP prototype. The experimental power consumption profile of the SWAMP during four missions is analysed to define the primary energy sources ratings of the Eco-SWAMP. After a commercial choice of primary sources, power management algorithms are designed and compared in MATLAB/Simulink environment by simulation results. The proposed procedure can be easily applied to any autonomous marine vehicle.     

Effective factors improving catalyst layers of PEM fuel cell

Cathode catalyst layer has an important role on water management across the membrane electrode assembly (MEA). Effect of Pt percentage in commercial catalyst and Pt loading from the viewpoint of activity and water management on performance was investigated. Physical and electrochemical characteristics of conventional and hydrophobic catalyst layers were compared. Performance results revealed that power density of conventional catalyst layers (CLs) increased from 0.28 to 0.64 W/cm² at 0.45 V with the increase in Pt amount in commercial catalyst from 20% to 70% Pt/C for H₂/Air feed. In the case of H₂/O₂ feed, power density of CLs increased from 0.64 to 1.29 W/cm² at 0.45 V for conventional catalyst layers prepared with Tanaka. Increasing Pt load from 0.4 to 1.2 mg/cm², improved kinetic activity at low current density region in both feeding conditions. Scattering electron microscopy (SEM) images revealed that thickness of the catalyst layers (CLs) increases by increasing Pt load. Electrochemical impedance spectroscopy (EIS) results revealed that thinner CLs have lower charge transfer resistance than thicker CLs. Inclusion of 30 wt % Polytetrafluoroethylene (PTFE) nanoparticles in catalyst ink enhanced cell performance for the electrodes manufactured with 20% Pt/C at higher current densities. However, in the case of 70% Pt/C, performance enhancement was not observed. Cyclic voltammetry (CV) results revealed that 20% Pt/C had higher (77 m²/g) electrochemical surface area (ESA) than 70% Pt/C (65 m²/g). In terms of hydrophobic powders, ESA of 30PTFE prepared with 70% Pt/C was higher than 30PTFE prepared with 20 %Pt/C. X-Ray Diffractometer (XRD) results showed that diameter of Pt particles of 20% Pt/C was 2.5 nm, whereas, it was 3.5 nm for 70% Pt/C, which confirms CV results. Nitrogen physisorption results revealed that primary pores of hydrophobic catalyst powder prepared with 70% Pt/C was almost filled (99%) with Nafion and PTFE.     

A rolling horizon simulation approach for managing demand with lead time variability

This paper proposes a rolling horizon (RH) approach to deal with management problems under dynamic demand in planning horizons with variable lead times using system dynamics (SD) simulation. Thus, the nature of dynamic RH solutions entails no inconveniences to contemplate planning horizons with unpredictable demands. This is mainly because information is periodically updated and replanning is done in time. Therefore, inventory and logistic costs may be lower. For the first time, an RH is applied for demand management with variable lead times along with SD simulation models, which allowed the use of lot-sizing techniques to be evaluated (Wagner-Whitin and Silver-Meal). The basic scenario is based on a real-world example from an automotive single-level SC composed of a first-tier supplier and a car assembler that contemplates uncertain demands while planning the RH and 216 subscenarios by modifying constant and variable lead times, holding costs and order costs, combined with lot-sizing techniques. Twenty-eight more replications comprising 504 new subscenarios with variable lead times are generated to represent a relative variation coefficient of the initial demand. We conclude that our RH simulation approach, along with lot-sizing techniques, can generate more sustainable planning results in total costs, fill rates and bullwhip effect terms.     

Mapping Sentiments to Themes of Customer reactions on Social Media during a Security Hack: A Justice Theory Perspective

As social media continues to transform firm–customer interactions, firms must leverage customer reactions to generate actionable insights, especially in contexts (e.g., crisis events) where customer reactions are critical. Using the justice theory, we categorize customer reactions of two firms, Home Depot and Target, during the time-frame of a security hack to understand key themes/topics. We then map the themes/topics to customer sentiments in those reactions. We found that customers associate justice with simple procedures than the experience of dealing with the firm. In addition, it is critical for firms to carefully assess and control customer sentiments on social media during crisis events.     

时空四维动态分析在采场及生产接续管理中的应用

时空四维动态分析管理理念是通过对矿井采场布局情况的精准分析,结合采场空间布置和时间布局,找出干涉点、影响点、关键点和突出问题,对生产布局情况进行动态循环调整,保障采场接续正常,为矿井长远稳定发展提供理论基础。     

施工现场标准化管理探讨

通过对神华宁煤400万t/a煤化工副产品深加工综合利用项目60万t/a聚丙烯装置施工作业现场的标准化研究,从技术团队的选择、计划进度控制、现场施工管理、文档资料规范等几个方面,探讨施工作业现场标准化作业的方法,为提高施工作业现场管理提供一些有益的建议。     

五大发展理念视角下的南流江流域综合管理研究

随着"创新、协调、绿色、开放、共享"五大发展理念的提出,广西壮族自治区在新时期对重要江河的流域管理方面有了新的要求。为了适应新的发展理念,以南流江流域为例,开展了流域综合管理方面的专项分析研究。研究发现,南流江流域存在着水文灾害多发、环境污染较严重、地下水超采、水土流失等一些自然问题以及法律法规不健全、流域管理机构单薄、规划不完善、忽视公众力量和缺乏新技术支撑等一些社会管理方面的问题,在这种背景下以前的流域管理模式显然已不再适用。因此,针对研究结果,基于五大发展理念,借鉴国外成功的经验并结合南流江流域的实际情况提出了一些相应的对策与建议,以提升流域的综合管理水平。